BPAL-1: Certified Reference Material of carbon-13 labelled bisphenol A

The following tables show those constituents for which certified and information values have been established for this [13C5]-bisphenol A certified reference material (CRM).

The certified value shows the purity of [13C5]-bisphenol A. Certified and information values are based on results from data generated at NRC using quantitative proton nuclear magnetic resonance spectroscopy (1H-qNMR). The expanded uncertainty (UCRM) in the certified value is equal to U = kuc where uc is the combined standard uncertainty calculated according to the JCGM Guide and k is the coverage factor. A coverage factor of two (2) was applied. It is intended that UCRM accounts for every aspect that reasonably contributes to the uncertainty of the measurement.

Table 1: Certified values for BPAL-1

Substance Molecular formula Mass fraction, g/g
[13C5]-bisphenol A 13C5C10H16O2 0.9969 ± 0.0040

Table 2: Information values for impurities in BPAL-1

Substance CAS Number Molecular formula Mass fraction, g/g
[13C8]-4-(2,2,4-trimethyl-4-chromanyl)-phenol 472-41-3 13C8C10H20O2 0.000 30
[13C5]-4,3’-(propane-2,2-diyl)-diphenol N/A 13C5C10H16O2 0.000 29
toluene 108-88-3 C7H8 0.000 50

Intended use

This reference material is primarily intended for use in the calibration of procedures and the development of methods for the determination of bisphenol A. A minimum sample mass of 2 mg is recommended.

Storage

It is recommended that the material be stored at 4 oC or lower.

Uncertainty

Included in the combined uncertainty estimate (uc) are uncertainties in the batch characterization (uchar), uncertainties related to possible between-bottle variation (uhom), short-term stability (ustability) and uncertainties related to variability between the different qNMR signals (umethod). Expressed as standard uncertainties, these components are listed in Table 3.

Table 3: Uncertainty components for BPAL-1

Substance uk=2
g/g
uc
g/g
uchar
g/g
uhom
g/g
ustability
g/g
umethod
g/g
[13C5]-bisphenol A 0.0040 0.0020 0.0018 0.0008 0.0000 0.0000

Date of issue: September 2017
Date of expiry: March 2020

Date modified: