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Laser-Induced Breakdown Spectroscopy (LIBS)

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Optical Sensing Technology for Rapid On-site Chemical Analysis

Many attributes of the LIBS technique make it ideal for rapid on-site analysis of solid, liquid, or gas. The LIBS team at IMI, one of the most active worldwide, is pushing the limits of the technology, collaborating with industry to meet new challenges, developing prototype instruments for use at industrial sites and continuing its pioneering work in the pharmaceutical sector in collaboration with its spin-off company, Pharma Laser.

The LIBS Technique

When a powerful laser beam is focused on a sample, some matter is vaporized and a hot spark (plasma) is formed. Light emitted by the plasma is composed of spectral lines characteristic of the elements present in the sample. By spectrally analyzing this light, it is possible to deduce the elemental composition of the material under study. Moreover, the proportionality of spectral line intensity to elemental concentration enables quantitative analysis. The main attributes of this technique are:

  • Solids, liquids and gases can be analyzed without sample preparation

  • In-situ, real-time (rapid) analysis

  • Stand-off analysis (only optical access is required)

  • Field-portable

  • High resolution (mm)

Laser-Induced Breakdown Spectroscopy (LIBS)

LIBS Applications

LIBS now has demonstrated capabilities for the detection and quantification of analytes in a large range of matrices.

Solids

  • metals
  • ceramics
  • semiconductors
  • polymers
  • pharmaceuticals
  • teeth
  • soils
  • minerals
  • bacteria on agar substrate
  • metals immersed in water
  • wood, paper

Liquids

  • molten metals, salts and glass
  • industrial effluents§ process liquids
  • pharmaceutical preparations§
  • biological fluids
  • water (environment)
  • colloid

Gases

  • industrial exhaust streams
  • combustion environments (coal-fired facility)
  • aerosols in ambient air
  • proof-of-concept for detection of chemical warfare agents

LIBS instrument for pharmaceutical industry commercialized by Pharma Laser
LIBS instrument for pharmaceutical industry commercialized by Pharma Laser
(Photo - Compliments of Pharma Laser)

LIBS measurement for in-plant continuous monitoring of residual metal in aqueous process effluents
LIBS measurement for in-plant continuous monitoring of residual metal in aqueous process effluents



LIBS at the Industrial Materials Institute

Metallurgy

  • solid or molten alloys (Al, Cu, Zn, Mg, steel, Co, Ni, Cr)
  • process fluids
  • galvanized steel
  • molten salts
  • depth profiling

Pharmaceuticals

  • analysis of drug and lubricant in tablets
  • analysis of saline solution
  • drug mapping
  • homogeneity of samples

Minerals

  • detection of various elements (Au, Cu, Ni, Fe, C, Ca, Al, Mg, Si, Ti) in ore and ore slurry

Environment

  • detection of contaminants
  • industrial effluents

Other Organics

  • paper
  • polymer
  • wood

Many of our industrial partners have achieved high return on investment through increased productivity or cost reduction by using the LIBS technology.

Online measurements of additives in iron ore slurry
Online measurements of additives in iron ore slurry
(Photo - Compliments of IOC Inc.)

Recent Scientific and Technological Developments

In addition to industrial applications and prototype development, the LIBS team at IMI is also carrying out basic research aimed at lowering the detection limits of LIBS from the ppm to the ppb range and at widening its range of applicability. This R&D effort has led to new intellectual property. Here are examples of recent developments:

  • increase in sensitivity by 1 to 2 orders of magnitude using double-pulse laser bursts or mixed-wavelength pulses
  • LIBS analysis of multilayer samples with high depth resolution
  • micro-mapping of heterogeneous samples
  • one-shot multielemental analysis using Échelle spectrograph
  • tunable laser for selective atomic excitations
  • combination of LIBS with other spectroscopic techniques, such as fluorescence or Raman scattering
  • use of femtosecond laser for LIBS applications

Partnership Opportunities

The LIBS team at IMI strongly encourages collaborative R&D with industry, academia and other governmental agencies. We offer services ranging from precompetitive R&D to specific feasibility studies, as well as development and in-plant installation of prototypes adapted to specific manufacturing needs

Dr. Mohamad Sabsabi
Research Officer, Optical Techniques Group
Modelling and Diagnostics Section
Tel. : (450) 641-5113
Fax : (450) 641-5106
E-mail: Mohamad.Sabsabi@cnrc-nrc.gc.ca

Photography of Mohamad Sabsabi

Ngoc Huynh, Eng., M.A.Sc., M.B.A.
Business Development Officer
Modelling and Diagnostics Section
Tel. : (450) 641-5135
Fax : (450) 641-5106
E-mail: Ngoc.Huynh@cnrc-nrc.gc.ca

Photo of Ngoc Huynh

Related Information

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